The Temperature Entropy Diagram

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Vol.
--- wxp.
But each substance possesses at the temperature t its own specific volume, so that there is one value of wv, say WiVi, which will be smaller than all the other values of wv. That is, this particular substance will be the first to have its liquid vaporized. At the moment this occurs Vol. = whence X2= ~~' X3= ~ xr M xr\ r*i /M TI J. 2 J-3 etc. , etc.
Any further increase in volume at this temperature would mean superheating of Wi with consequent drop of pressure pi, that is, p M wou
...ld decrease. This, how- ever, is inconsistent with the assumption of constant pressure, so that the temperature would begin to rise MIXTURES OF GASES AND VAPORS. 151 again in such a manner that the rise in pressure of P2 + P3+P4+.

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