The Theory of Heat

Cover The Theory of Heat
The Theory of Heat
Thomas Preston
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Matthiessen, taking the volume to be unity at 4° C, adopted the formula between + 4"* and 32° where a=0-00000258, 6=0-000008389, c= 000000007178, and for temperatures between 32 and 100, the formula V=0-999696^ + 0*0000054724^-0*00000001126^.
M. Bosetti in turn adopted a formula of the more general form V=l+a(^-4)«+6(^-4)^+c(^-4)y.
Such formulae, however, can scarcely be regarded as having any theoretic importance. They merely represent more or less approxi- mately the general results of experi
...ments from which their constants have been determined, and their value depends upon how closely they represent the whole series of experiments. .
Recently D. Mendel6eff^ has proposed a formula for the density of water between - 10° and + 200° C. of the form the density at 4° being unity. A general formula, supposed to apply to all liquids, had been previously given by the same physicist * giving the density at any temperature 6 in the form Such a formula, of course, cannot embrace such cases as the anomalous expansio[i of water at 4°, for unless k be supposed also a function of the temperature, the density will continually decrease as the temperaturo rises.


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