The Viscosity of Liquids
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Measurement showed that the lower melting, more soluble isomer had the lower viscosity and this form therefore will have the ad- jacent constitution I. By analogy with other camphor deriva- tives, though without any direct evidence, this same configuration was assigned by Forster and Zimmerli 125 . The configurations of the benzaldehyde phenylhydrazones have been proved by chemi- cal means and the adjacent form possesses the higher viscosity, showing that the effect due to potential ring format...ion is greater than that due to inhibition of association. This is due to the small residual affinity of the phenyl group as compared with that of the carbonyl group in the case just considered.
With the data now available one can approach the difficult problem of the configuration of the two acetaldehyde phenyl- hydrazones. If ordinary acetaldehyde phenylhydrazone is crystal- 86 THE VISCOSITY Of LIQUIDS lized from alcohol containing a trace of acid it separates as the so- called form melting at 56.
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You can find similar books in the "Read Also" column, or choose other free books by A E Albert Ernest Dunstan to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
Measurement showed that the lower melting, more soluble isomer had the lower viscosity and this form therefore will have the ad- jacent constitution I. By analogy with other camphor deriva- tives, though without any direct evidence, this same configuration was assigned by Forster and Zimmerli 125 . The configurations of the benzaldehyde phenylhydrazones have been proved by chemi- cal means and the adjacent form possesses the higher viscosity, showing that the effect due to potential ring format...ion is greater than that due to inhibition of association. This is due to the small residual affinity of the phenyl group as compared with that of the carbonyl group in the case just considered.
With the data now available one can approach the difficult problem of the configuration of the two acetaldehyde phenyl- hydrazones. If ordinary acetaldehyde phenylhydrazone is crystal- 86 THE VISCOSITY Of LIQUIDS lized from alcohol containing a trace of acid it separates as the so- called form melting at 56.
What to read after The Viscosity of Liquids?
You can find similar books in the "Read Also" column, or choose other free books by A E Albert Ernest Dunstan to read onlineMoreLess
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