Theoretical Principles of the Methods of Analytical Chemistry Based Upon Chemica

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Theoretical Principles of the Methods of Analytical Chemistry Based Upon Chemica
G Gabriel Chesneau
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If there is then added to the sulphuric acid just the quantity of barium chloride corresponding to the preceding equation, there will remain in solution a small quantity of barium chloride, sulphuric acid and barium sulphate conforming to the isothermal equation of equilibrium >' L BaS0 4 and consequently, a little sulphuric acid will remain unprecipitated.
Let us now add an excess of barium chloride which increases Cg a Q 2 . In order that the equilibrium be maintained, it is necessary that CH
... 2 S0 4 diminish, or that C H *C1 increase, since C^sO* cannot increase, the solution being saturated with barium sulphate. Now, in order that the concentration of sulphuric acid should dimin- ish or that the concentration of hydrochloric acid should increase, it is necessary that a new quantity of barium sulphate should pre- cipitate. Thus the excess of the reagent, barium chloride, will ren- der the precipitation of the sulphuric acid more complete. Likewise, if we wish to precipitate all the barium contained in a solution, it will be necessary for the same reason, to add an excess of sulphuric acid.

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