Theoretical Principles of the Methods of Analytical Chemistry Based Upon Chemica
Theoretical Principles of the Methods of Analytical Chemistry Based Upon Chemica
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If there is then added to the sulphuric acid just the quantity of barium chloride corresponding to the preceding equation, there will remain in solution a small quantity of barium chloride, sulphuric acid and barium sulphate conforming to the isothermal equation of equilibrium >' L BaS0 4 and consequently, a little sulphuric acid will remain unprecipitated.
Let us now add an excess of barium chloride which increases Cg a Q 2 . In order that the equilibrium be maintained, it is necessary that CH... 2 S0 4 diminish, or that C H *C1 increase, since C^sO* cannot increase, the solution being saturated with barium sulphate. Now, in order that the concentration of sulphuric acid should dimin- ish or that the concentration of hydrochloric acid should increase, it is necessary that a new quantity of barium sulphate should pre- cipitate. Thus the excess of the reagent, barium chloride, will ren- der the precipitation of the sulphuric acid more complete. Likewise, if we wish to precipitate all the barium contained in a solution, it will be necessary for the same reason, to add an excess of sulphuric acid.
What to read after Theoretical Principles of the Methods of Analytical Chemistry Based Upon Chemica?
You can find similar books in the "Read Also" column, or choose other free books by G Gabriel Chesneau to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
If there is then added to the sulphuric acid just the quantity of barium chloride corresponding to the preceding equation, there will remain in solution a small quantity of barium chloride, sulphuric acid and barium sulphate conforming to the isothermal equation of equilibrium >' L BaS0 4 and consequently, a little sulphuric acid will remain unprecipitated.
Let us now add an excess of barium chloride which increases Cg a Q 2 . In order that the equilibrium be maintained, it is necessary that CH... 2 S0 4 diminish, or that C H *C1 increase, since C^sO* cannot increase, the solution being saturated with barium sulphate. Now, in order that the concentration of sulphuric acid should dimin- ish or that the concentration of hydrochloric acid should increase, it is necessary that a new quantity of barium sulphate should pre- cipitate. Thus the excess of the reagent, barium chloride, will ren- der the precipitation of the sulphuric acid more complete. Likewise, if we wish to precipitate all the barium contained in a solution, it will be necessary for the same reason, to add an excess of sulphuric acid.
What to read after Theoretical Principles of the Methods of Analytical Chemistry Based Upon Chemica?
You can find similar books in the "Read Also" column, or choose other free books by G Gabriel Chesneau to read onlineMoreLess
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