Theoretical Principles of the Methods of Analytical Chemistry Based Upon Chemical Reactions

Cover Theoretical Principles of the Methods of Analytical Chemistry Based Upon Chemical Reactions
Theoretical Principles of the Methods of Analytical Chemistry Based Upon Chemical Reactions
G Gabriel Chesneau
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Ostwald, Die Wissenschaftlichen Grundlagen des anal. Chemie, p. 54- {Foundations of Analytical Chemistry, translated by Geo. McGowan, 3d English ed. igo8> p. 57.— Editors? Note.) Digitized by VjOOQ IC BASED UPON CHEMICAL REACTIONS 105 acid, sulphureted hydrogen, hydrocyanic, silicic and boric acid.
The dissociation of the last two is scarcely measurable.
The strong bases are, like the strong acids, almost completely ionized. They are the hydroxides of the alkali and alkaline earth metals and th
...e organic quarternary ammonium bases. The moder- ately strong bases are ammonium hydroxide and the amine bases, the hydroxides of silver and magnesium. Finally, the weak bases, which are scarcely ionized, comprise the other metallic hydroxides, the amines of the aromatic series (in which the nitrogen is linked to the aromatic nucleus) and the greater number of the alkaloids.
The metallic salts present, in general, much less variation in the degree of ionization than the free acids and bases. The neutral salts of the strong acids and bases are almost completely ionized ; those of the moderately strong acids and bases are almost as greatly ionized as the strong acids and bases, for example, ammonium acetate is about seventy-five per cent dissociated.


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