Theories of Organic Chemistry
Theories of Organic Chemistry
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Chemie, 7, 140 (1891); Jour, prakt. Chemie, 60, 152 (1894). 298 THEORIES OF ORGANIC CHEMISTRY The difference between these two formulas may be expressed in terms of atomic refractions and increments as follows: C 6 Hi O20< and C 6 HioO"OO< [f If the molecular refraction of each of these is calculated for light of wave length D the following results are obtained : Keto Form Enol Form C 6 = 6X2. 418 = 14. 508 C 6 = 6X2. 418 = 14. 508 H 10 =10X1. 100 = 11. 000 H 10 =10X1. 100 = 11. 000 O2 = 2X2. 211= 4. 422 O" = 1X2. 211= 2. 211 O<= 1X1. 643= 1. 643 O' = 1X1. 525= 1. 525 O<= 1X1. 643= 1. 643 IT = 1X1. 733= 1. 733 Mol . Refraction = 3 1 . 573 Mol . Refraction = 32 . 620 The molecular refraction for ordinary ethyl acetoacetate as deter- mined at room temperature has been found to be Jlf = 32. 00. 1 This value is obviously intermediate between the calculated values for the keto and end, respectively, although it approximates the former more closely than the latter. These results thus tend to confirm chem- ical investigation in the matter since they indicate that liquid ethyl acetoacetate consists of a mixture which contains a large amount of the keto modification together with small quantities of ethyl /3-hydroxycrotonate.
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To quickly assess the difficulty of the text, read a short excerpt:
Chemie, 7, 140 (1891); Jour, prakt. Chemie, 60, 152 (1894). 298 THEORIES OF ORGANIC CHEMISTRY The difference between these two formulas may be expressed in terms of atomic refractions and increments as follows: C 6 Hi O20< and C 6 HioO"OO< [f If the molecular refraction of each of these is calculated for light of wave length D the following results are obtained : Keto Form Enol Form C 6 = 6X2. 418 = 14. 508 C 6 = 6X2. 418 = 14. 508 H 10 =10X1. 100 = 11. 000 H 10 =10X1. 100 = 11. 000 O2 = 2X2. 211= 4. 422 O" = 1X2. 211= 2. 211 O<= 1X1. 643= 1. 643 O' = 1X1. 525= 1. 525 O<= 1X1. 643= 1. 643 IT = 1X1. 733= 1. 733 Mol . Refraction = 3 1 . 573 Mol . Refraction = 32 . 620 The molecular refraction for ordinary ethyl acetoacetate as deter- mined at room temperature has been found to be Jlf = 32. 00. 1 This value is obviously intermediate between the calculated values for the keto and end, respectively, although it approximates the former more closely than the latter. These results thus tend to confirm chem- ical investigation in the matter since they indicate that liquid ethyl acetoacetate consists of a mixture which contains a large amount of the keto modification together with small quantities of ethyl /3-hydroxycrotonate.
What to read after Theories of Organic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Ferdinand August Karl Henrich to read online
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