Theories of Solutions

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In the same manner the solution of a sohd in a Uquid must be explained as a consequence of molecular motion according to the mechanical theory of heat.
This idea was expressed by Tilden and Shenstone (1883) "The solution of a soUd in a liquid would accordingly be analogous to the subHmation of such a solid into a gas and proceeds from the intermixtiire of molecules detached from the sohd, with those of the surrounding Uquid. Such a process is promoted by rise of tempera- ture, partly because th
...e molecules of the stUl sohd substance make longer excursions from their normal centre, partly because they are subjected to more violent encounter with the moving molecules of hquid." . . . "Such a theory however, serves to account only for the initial stage in the process of solution, and does not explain the selective power of solvents nor the limitation of solvent power of a given Uquid." Walden cites Mendelejeff as a precursor of the sup- porters of an analogy between gases and dissolved substances.

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