Thermodynamic Properties of Multicomponent Mixtures From the Solution of Groups Approach to Direct Correlation Function Solution Theory
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In our eReader you can find the full English version of the book. Read Thermodynamic Properties of Multicomponent Mixtures From the Solution of Groups Approach to Direct Correlation Function Solution Theory Online - link to read the book on full screen. Our eReader also allows you to upload and read Pdf, Txt, ePub and fb2 books. In the Mini eReder on the page below you can quickly view all pages of the book - Read Book Thermodynamic Properties of Multicomponent Mixtures From the Solution of Groups Approach to Direct Correlation Function Solution Theory
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To quickly assess the difficulty of the text, read a short excerpt:
The important aspect of this approach is that the groups are dealt with as if they were all indepen- dent. This is not physically the situation. The dependence is caused by the intramolecular correlations, and they must be properly accounted for to yield an accurate model.
Originally it was believed that the RISM theory took account of this behavior, but as was mentioned in the preceding section, this is not true. Even the proper integral equation direct correlation functions, equation 7-3, whi...le short ranged, still involve intramolecular correlations due to third body effects. Cummings and Sullivan (1982a) explicitly show that while the h ag (r) functions are purely intermolecu- o "*" lar quantities that the c ag (r) are not.
The exact resummation of the cluster expansion for h g (r) shown by Chandler et al. (1982) suggests a way around the aforementioned difficulties. It should be possible to define a set of direct correlation functions, labeled here as c g (r), that include only intermolecular effects.
What to read after Thermodynamic Properties of Multicomponent Mixtures From the Solution of Groups Approach to Direct Correlation Function Solution Theory?
You can find similar books in the "Read Also" column, or choose other free books by Telotte, John Charles to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
The important aspect of this approach is that the groups are dealt with as if they were all indepen- dent. This is not physically the situation. The dependence is caused by the intramolecular correlations, and they must be properly accounted for to yield an accurate model.
Originally it was believed that the RISM theory took account of this behavior, but as was mentioned in the preceding section, this is not true. Even the proper integral equation direct correlation functions, equation 7-3, whi...le short ranged, still involve intramolecular correlations due to third body effects. Cummings and Sullivan (1982a) explicitly show that while the h ag (r) functions are purely intermolecu- o "*" lar quantities that the c ag (r) are not.
The exact resummation of the cluster expansion for h g (r) shown by Chandler et al. (1982) suggests a way around the aforementioned difficulties. It should be possible to define a set of direct correlation functions, labeled here as c g (r), that include only intermolecular effects.
What to read after Thermodynamic Properties of Multicomponent Mixtures From the Solution of Groups Approach to Direct Correlation Function Solution Theory?
You can find similar books in the "Read Also" column, or choose other free books by Telotte, John Charles to read onlineMoreLess
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