Thermodynamics An Introductory Treatise Dealing Mainley With First Principles a
Thermodynamics An Introductory Treatise Dealing Mainley With First Principles a
George Hartley Bryan
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When the value of the equilibrium constant is known for a given temperature and pressure, we can predict with accuracy the effect produced in the system by varying the con- centrations of the substances. On account of the great importance of the law of mass action, it may be worth while to derive it in a somewhat different manner. We shall not, however, consider the most general case, but merely deduce the law for a particular case, viz. : the reaction given by equation (9). We suppose then tha...t the volume V contains HI moles of H 2, n% moles of O 2 and HS moles of H 2 O at the temper- ature T and the total pressure p. We desire to bring about]the union of 2 moles of H 2 and i mole of oxygen to form 2 moles of H 2 in a thermodynamically reversible manner. We first imagine the three gases to be separated from each other so that we have n\ moles of pure H 2 at the pressure pi, n z moles of O 2 at the pressure p 2 and n s moles of water at the pressure p 3 . The CH. XV THE LAW OF MASS ACTION 253 temperature and volume of each gas are T and V.
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