Thermodynamics And Chemistry. a Non-Mathematical Treatise for Chemists And Students of Chemistry

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One might think this phenomenon comparable to those studied in Chapter XI, and that the point r is an indifferent point where two distinct liquid layers, but of the same composition, are in equi- librium with each other.
It is easy to be convinced that this supposition would be erro- neous.
If it were exact, we might say of the double liquid mixture formed by water and phenol all that has been said of the double mixture formed by a mixture of volatile liquids surmounted by the mixed vapor which
... it gives off; one of the two layers into which the double liquid mixture is separated would play the same r61e as the mixed liquid, the other layer would play the same role as the mixed vapor; if X and x were the compositions of the two layers capable of remaining in equilibrium in contact with each 316 THERMODYNAMICS AND CHEMISTRY.
other at the temperature T, the point M (Fig. 105) of coordinates T, X, would describe a curve with two branches CIC; the point m, of coordinates T, x, would describe another curve of two branches, clc' ; these two curves would pass through the point I, of coordinates 6, ?, and touch there a parallel to Ox; at a given temperature T, below d according to the masses of water and phenol employed, our double liquid mixture could possess two distinct states of equilibrium; in one, the two superposed layers would have the s T compositions A', x and the representative Fig.


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