Thermodynamics of Technical Gas-Reactions: Seven Lectures

Cover Thermodynamics of Technical Gas-Reactions: Seven Lectures
Thermodynamics of Technical Gas-Reactions: Seven Lectures
Fritz Haber
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A formula which would give such a value is A = -9650 -f 1-55TM - 0'00195T 2 - 00 X A simple transformation of this formula gives the above- mentioned expression, by means of which the numbers in the fifth column of the above table were calculated. They agree excellently with the observed values. The quantity CGO - cji 2 o becomes on this basis - T55 4- O00195T. This difference of the mean specific heats between abs. And T, computed as before for a series of temperatures, gives the numbers tG .......... 1227 1427 1627 1827 T ...... 1500 1700 1900 2100 Grara-ca). ... +1-37 + 1'76 +2-15 + 254 These numbers, both as regards magnitude and sign, are very close to those which we previously found from the results of Mallard and Le Chatelier, Langen and Schreber. Since it is precisely this interval (between 1300 and 1700) which is best studied, the agreements of our assumption with the other formulae gives it added support. According to our formula, the sign of the difference changes at 522. This does not agree with the results of Holborn and Austin and of Holborn and Henning.

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