Victor Von Richter's Organic Chemistry ; Or, Chemistry of the Carbon Compounds
Victor Von Richter's Organic Chemistry ; Or, Chemistry of the Carbon Compounds
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In our eReader you can find the full English version of the book. Read Victor Von Richter's Organic Chemistry ; Or, Chemistry of the Carbon Compounds Online - link to read the book on full screen. Our eReader also allows you to upload and read Pdf, Txt, ePub and fb2 books. In the Mini eReder on the page below you can quickly view all pages of the book - Read Book Victor Von Richter's Organic Chemistry ; Or, Chemistry of the Carbon Compounds
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The most suitable oxidants are chromic acid, dilute nitric acid, potassium permanganate, and potassium ferricyanide.
(a) Oxidation with Chromic Add, — Only the para- and meta-derivatives (the former more readily than the latter^ of benzenes, carrying two side-chains, are oxidized to acids by chromic acid, while the ortho- are either not attacked at all or are completely destroyed.
In snbstitnted alkyl benzenes the alkyl -group is prevented from being oxidized by chromic acid, if a negative grou...p occup3ring the o-position with reference to the alkyl - group is present (B. 15, 1021). The oxidations are conducted either with free chromic acid in glacial acetic acid, or with a mixture of potassium bichromate (3 parts) and sul- phuric add (3 parts), diluted with 2-3 volumes of water.
(h) Oxidation with Nitric Acid, — When oxidizing with nitric acid use acid diluted with 3 parts of water and boil for some time, hi connection with a return condenser (2-3 days). Kooowaloff (p. 178) contends that phenylnitroparaffins are 6rst produced ; these then are farther oxidized to carboxylic acids.
What to read after Victor Von Richter's Organic Chemistry ; Or, Chemistry of the Carbon Compounds?
You can find similar books in the "Read Also" column, or choose other free books by Victor Von Richter to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
The most suitable oxidants are chromic acid, dilute nitric acid, potassium permanganate, and potassium ferricyanide.
(a) Oxidation with Chromic Add, — Only the para- and meta-derivatives (the former more readily than the latter^ of benzenes, carrying two side-chains, are oxidized to acids by chromic acid, while the ortho- are either not attacked at all or are completely destroyed.
In snbstitnted alkyl benzenes the alkyl -group is prevented from being oxidized by chromic acid, if a negative grou...p occup3ring the o-position with reference to the alkyl - group is present (B. 15, 1021). The oxidations are conducted either with free chromic acid in glacial acetic acid, or with a mixture of potassium bichromate (3 parts) and sul- phuric add (3 parts), diluted with 2-3 volumes of water.
(h) Oxidation with Nitric Acid, — When oxidizing with nitric acid use acid diluted with 3 parts of water and boil for some time, hi connection with a return condenser (2-3 days). Kooowaloff (p. 178) contends that phenylnitroparaffins are 6rst produced ; these then are farther oxidized to carboxylic acids.
What to read after Victor Von Richter's Organic Chemistry ; Or, Chemistry of the Carbon Compounds?
You can find similar books in the "Read Also" column, or choose other free books by Victor Von Richter to read onlineMoreLess
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