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From very dilute aqueous amido- benzene m-sulphonic acid and bromine-water (Langfurth, A. 191, 176). 5. From (1, 3, 4, 6)-di- bromo-w-amido-benzene sulphonic acid, fuming HC1, and red P at 150 (Limpricht, B. 10, 1542). 6. By heating the same acid with water at 250 (L. ). Properties. Anhydrous needles (from cone, aqueous solution) or four- and six-sided columns containing aq (from dilute solution). SI. Sol. Alcohol. Keduced by HI and P, or by water at 120, to amido-benzene m-sulphonic acid. S al... t s. KA'l aq (La. ). KA' aq (Spiegelberg, A. 197, 257). BaA' 2 aq. BaA' 2 3aq. S. (ofBaA' 2 ) 6-22 at 17. PbA' 2 . CaA' 2 2aq. AgA' laq. (1, 4, 3)-Bromo-amido-benzene sulphonic acid C u H, Br(NH 2 )S0 3 H [1:4:3]. S. -47 at 15. Formation. I. By heating ^-bromo-aniline ethyl-sulphate (Nolting, B. 8, 1095). 2. By adding bromine to a cold aqueous solution of barium aniline o-sulphonate (Limpricht, A. 181, 196). 3. By nitration and reduction of bromo- benzene m-sulphonic acid (Thomas, A. 186, 126).
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