Zinc Nitride, Its Formation, Properties And Alloys

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Analysis showed Ofo N.
The brown powder v/hich formed on top of the zinc nitride was brought about by the impurities in the ammonia which had not been taken out. As zinc nitride decomposes faster at the higher temperatures we believe that the greater the rapidity with which the product is cooled down the larger the yield of nitride.
12.
Run No, 2 With Purified Gases.
This run was made to see what effect the elimination of oxygen from the gases would have upon the quantity of zinc nitride formed
....
A fresh solution of alkaline pyrogallate was added to the absorbent trains to take out whatever oxygen may have been present in the gases, in other respects the run was similar to the previous ones. Hydrogen was passed for thirty minutes at 400°, ammonia for thirty minutes at 600*^, and then nitrogen was passed through during the cooling period. We believed the nitrogen, after the elimination of oxygen to be a purer product than the ammonia.
The first and second boats contained a uni- form powder very dark gray in color.


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